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Self-Assembly of a Molecular Floral Lace with One-Dimensional Channels and Inclusion of Glucose
Hye Jin Choi1, Taek Soon Lee1, Myunghyun Paik Suh1
1Department of Chemistry Education and Center for Molecular Catalysis, Seoul National University, Seoul 151-742 (Republic of Korea), Fax: (+82) 2-8890749.
Abstract:
A three-dimensional network with one-dimensional channels (see picture) has been self-assembled from the nickel(II) complex of cyclam and 1,3,5-benzenetricarboxylate in water through hydrogen-bond formation. The channels have an appropriate diameter (10.3 Å) to include D-glucose with a formation constant of Kf =(1.38±0.01)×104 M-1 . Under similar conditions maltose is not included.
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