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Published on: May 22, 2018
A Belted Monofacial Ionophore Featuring High Selectivity for Lithium Ion Complexation
Leo A Paquette1, Jinsung Tae1, Eugene R Hickey1
1Evans Chemical Laboratories, The Ohio State University, Columbus, OH 43210 (USA), Fax: (+1) 614-292-1685.
Abstract:
Despite its preferred equatorial conformation in the solid state and in solution, the cis,cis-trispiro ether 1 binds readily and strongly to lithium ions. The 2:1 sandwich complex 2 is initially formed and transformed progressively into the 1:1 species 3 upon the addition of more LiClO4 .
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