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Updated: Feb 11, 2026

Utilizing the Ethylene-releasing Compound, 2-Chloroethylphosphonic Acid, as a Tool to Study Ethylene Response in Bacteria
Published on: November 10, 2016
Reversible Fixation of Ethylene on a SmII Calix-Pyrrole Complex
Tiffany Dubé1, Sandro Gambarotta1, Glenn P A Yap1
1Department of Chemistry, University of Ottawa, Ottawa, ON, K1N 6N5 (Canada), Fax: (+1) 613-562-5170.
Abstract:
Reversible ethylene fixation in lanthanide chemistry is demonstrated by the SmII derivatives [R8 -calix-pyrrole)(Et2 O)Sm{Li(thf)2 }{Li(μ3 -OCH=CH2 )}] (R=Et, {-(CH2 )5 -}0.5 ), which react with ethylene to afford the corresponding dinuclear complexes (see picture).
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