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Updated: Feb 11, 2026

Determination of Thermodynamic Properties of Alkaline Earth-liquid Metal Alloys Using the Electromotive Force Technique
Published on: November 3, 2017
Calcium, Strontium, and Barium Acetylides-New Evidence for Bending in the Structures of Heavy Alkaline Earth Metal
David C Green1, Ulrich Englich1, Karin Ruhlandt-Senge1
1Department of Chemistry, 1-014 Center for Science and Technology, Syracuse University, Syracuse NY 13244-4100 (USA), Fax: (+1) 315-443-4070.
Abstract:
An unprecedented ligand bending mode is displayed by the acetylide ligands in the first structurally characterized σ-bound organometallic strontium and barium complexes [M([18]crown-6)(CCSiPh3 )2 ] (M=Sr, Ba). Furthermore, the observed decrease of the angle at the sp-hybridized C atom on descending Group 2 (see structures depicted) affords new information that will lead to a better understanding of the bonding in alkaline earth metal compounds.
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