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Published on: August 18, 2023
First Synthesis and Structure of a Tetraazasilafenestrane
Bangwei Ding1, Reinhart Keese1, Helen Stoeckli-Evans2
1Departement für Chemie und Biochemie der Universität, Freiestrasse 3, CH-3012 Bern (Switzerland), Fax: (+41) 31-631-3423.
Abstract:
A shift from the computational to the synthetic side has taken place in the quest for compounds containing planar-tetracoordinate silicon: The first tetraazasilaspiro[4.4]nonane with two alkylene bridges has been prepared [Eq. (1)]. According to the X-ray structure analysis, the angle between the two diazasilacyclopentene rings is 84.7°. AIBN=azobisisobutyronitrile, X=Br.
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