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Determination of the Electron Density Distribution in the Bonds of a Fullerene Derivative by High-Resolution X-Ray
Hermann Irngartinger1, Anton Weber1, Thomas Oeser1
1Organisch-chemisches Institut der Universität, Im Neuenheimer Feld 270, D-69120 Heidelberg (Germany), Fax: (+49) 6221-544205.
Abstract:
Bent bonds in the strained fullerene system, restricted to the [5,6] bonds, were detected by high-resolution X-ray structure analysis of the 1,2-dihydro[60]fullerene derivative 1. In addition the maxima of electron densities are higher in the [6,6] bonds than in the [5,6] bonds-an important finding with respect to the question of the extent of electron delocalization in fullerenes.
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