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[M3 V18 O42 (H2 O)12 (XO4 )]⋅24 H2 O (M=Fe, Co; X=V, S): Metal Oxide Based Framework Materials Composed of
M Ishaque Khan1, Elizabeth Yohannes1, Robert J Doedens2
1Department of Biological, Chemical, and Physical Sciences, Illinois Institute of Technology, Chicago, IL 60616 (USA), Fax: (+1) 312-567-3494.
Abstract:
New framework materials composed of well-defined vanadium oxide clusters were prepared by low-temperature reactions and characterized by X-ray crystal structure analysis. The structures of these solids contain {V18 O42 } cages linked into two interpenetrating three-dimensional networks by bridging {M(H2 O)4 } groups (M=FeII , CoII ; see picture).
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