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Cyclic Hexamer with a Cubic Cavity: Crystal Structure of [{Rh(6-Purinethione Ribosido)(Cp*)}6 ](CF3 SO3 )6
Kazuaki Yamanari1, Shiori Yamamoto1, Rie Ito1
1Department of Chemistry, Graduate School of Science Osaka University 1-16 Machikaneyama-cho, Toyonaka, Osaka 560-0043 (Japan) Fax: (+81) 6-6850-5785.
Abstract:
The stereoselective formation of a pseudo-S6 hexamer resulted from the self-assembling reaction between [Rh(Cp*)(H2 O)3 ]2+ and 6-purinethione riboside (see left structure; Cp*=C5 Me5 ). The schematic representation (right) shows the direction of the coordination to the S6 and N(7) donor atoms. C (clockwise) and A (anticlockwise) indicate the chirality of each unit complex.
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