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Hydrophobic Pockets in a Nonpolymeric Aqueous Gel: Observation of such a Gelation Process by Color Change
Uday Maitra1, Samrat Mukhopadhyay1, Arnab Sarkar1
1Department of Organic Chemistry Indian Institute of Science Bangalore 560 012 (India) Fax: (+91) 80-360-1968.
Abstract:
Efficient gelation of aqueous fluids by a novel tripodal trischolamide generates chiral hydrophobic pockets in the gel network. A yellow to green color change (see absorbance spectra) in the presence of bromophenol blue (BPBH) indicates the formation of the gel. The bound (anionic) dye (BPB- ) shows induced circular dichroism, which is indicative of a chiral environment.
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