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E(SiMe3 )4+ Ions (E=P, As): Persilylated Phosphonium and Arsonium Ions
Matthias Driess1, Rainer Barmeyer1, Christian Monsé1
1Lehrstuhl für Anorganische Chemie I Molekül- und Koordinationschemie Ruhr-Universität Bochum Universitätsstrasse 150, 44801 Bochum (Germany) Fax: (+49)234-32-14378.
Abstract:
Only strong Lewis acidic, arene-solvated Me3 Si+ ions react with E(SiMe3 )3 compounds (E=P, As) to give the crystallographically characterized E(SiMe3 )4+ onium ions 1 (left hand picture), which contain highly negative polarized P and As atoms, respectively. The masked Me3 Si+ ions in 1 can be easily transferred to Et2 O, to give the first structurally characterized planar silyloxonium ion [Et2 (Me3 Si)O]+ 2 (right hand picture).
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