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Updated: Feb 11, 2026

Chemical Precipitation Method for the Synthesis of Nb2O5 Modified Bulk Nickel Catalysts with High Specific Surface Area
Published on: February 19, 2018
Nickel(II) Phosphate VSB-5: A Magnetic Nanoporous Hydrogenation Catalyst with 24-Ring Tunnels
Nathalie Guillou1, Qiuming Gao1, Paul M Forster2
1Institut Lavoisier, UMR CNRS C 8637 Université de Versailles Saint-Quentin-en-Yvelines 45 avenue des Etats-Unis, 78035 Versailles Cedex (France) Fax: (+33) 1-39-25-43-58.
Abstract:
Nanoporosity, good thermal stability, antiferromagnetic ordering, and hydrogenation with basic catalytic character are four important properties of the large-pore (24MR), zeolitic nickel(II) phosphate, VSB-5 (Ni20 [(OH)12 (H2 O)6 ][(HPO4 )8 (PO4 )4 ]⋅12 H2 O), which has been prepared under alkaline hydrothermal conditions. The structure of VSB-5 is depicted: NiO6 octahedra: green; PO4 tetrahedra: red.
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