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Double Photoionization of Dimethylaminobenzonitrile in Solution: A Three-Quantum Process with Intervening Chemical
Martin Goez1, Valentin Zubarev1
1Fachbereich Chemie Martin-Luther-Universität Halle-Wittenberg Kurt-Mothes-Strasse 2, 06120 Halle/Saale (Germany) Fax: (+49) 345-55-27-657.
Abstract:
Startling facts are often revealed by the quantitative investigation of a reaction thought to be understood. The photoionization of dimethylaminobenzonitrile, which was previously regarded as biphotonic, was found to occur by the successive absorption of three photons, and to produce two electrons per starting molecule [Eq. (1)]. The explanation is an intervening rapid chemical reaction: deprotonation followed by intramolecular charge transfer.
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