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Transition Metal Complexes with the Proton Sponge 4,9-Dichloroquino[7,8-h]quinoline: Highly Twisted Aromatic Systems
Hans-Ulrich Wüstefeld1, William C Kaska2, Ferdi Schüth1
1Max-Planck-Institut für Kohlenforschung Kaiser-Wilhelm-Platz 1, 45470 Mülheim/Ruhr (Germany) Fax: (+49) 208-306-2995.
Angewandte Chemie (International Ed. in English)
|May 2, 2018
Abstract:
An extremely high thermal and chemical stability as well as a unique "out-of-plane" position of the metal atom is shown by the first stable transition metal complexes formed with the proton sponge 1 as the ligand. The properties of these complexes await wide application in catalysis and medicine.