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A Redox Switch Based on Dihydro[5]helicene: Drastic Chiroptical Response Induced by Reversible C-C Bond
Jun-Ichi Nishida1, Takanori Suzuki1, Masakazu Ohkita1
1Division of Chemistry Graduate School of Science Hokkaido University, Sapporo 060-0810 (Japan) Fax: (+81) 11-746-2557.
Abstract:
Helicity and axial chirality are reversibly interconverted in the novel redox pair 1 and 22+ ; the compounds exhibit drastic UV/Vis and circular dichroism spectral changes as well as dynamic structural changes upon electron transfer, thus furnishing an unprecedented multi-output response system with high bistability. X=S or O.
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When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
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