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Updated: Feb 11, 2026

Synthesis of 1,2-Azaborines and the Preparation of Their Protein Complexes with T4 Lysozyme Mutants
Published on: March 25, 2017
Mononuclear η2 (4e)-Bonded Phosphaalkyne Complexes; Selective Formation of a 1,2-Diphosphacyclobutadiene Tantalum
Andrew D Burrows1, Alk Dransfeld2, Michael Green3
1Department of Chemistry, University of Bath Bath, BA2 7AY (UK).
Abstract:
Only the 1,2-diphosphacyclobutadiene and none of its 1,3 isomer was obtained in the reaction of 1 with tBuC≡P to give 2. In complex 1, which was prepared from [TaCl2 (η5 -C5 Me5 )(CO)2 (thf)] and tBuC≡P, the phosphaalkyne adopts an η2 (4e) bonding mode according to NMR data, crystal structure analysis, and theoretical calculations.
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