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NaBa2 O: A Fresh Perspective in Suboxide Chemistry
Grigori V Vajenine1, Arndt Simon1
1Max-Planck-Institut für Festkörperforschung Heisenbergstrasse 1, 70569 Stuttgart, Germany, Fax: (+49) 711-689-1642.
Abstract:
Linear $\rm{^{1}_{\infty }}$[Ba4/2 O] chains of edge-sharing Ba4 O tetrahedra are separated by sodium atoms in the crystal structure of the new sodium barium suboxide NaBa2 O. The metal-rich compound is held together by a combination of ionic and metallic bonding according to the formulation Na+ (Ba2+ )2 O2- ⋅3 e- .
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