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Updated: Feb 11, 2026

Author Spotlight: A Rapid, Microwave-Assisted Hydrothermal Synthesis Of Nickel Hydroxide Nanosheets
Published on: August 18, 2023
Sodium Tetra-tert-butylcyclopentaphosphanide: Synthesis, Structure, and Unexpected Formation of a Nickel(0)
Andrea Schisler1, Peter Lönnecke1, Uwe Huniar2
1Institut für Anorganische Chemie der Universität Leipzig Johannisallee 29, 04103 Leipzig, Germany, Fax: (+49) 341-9739319.
Abstract:
Forming a phosphorus envelope: The first structurally characterized cyclooligophosphanide ion [cyclo-(P5 tBu4 )]- to be obtained by a targeted synthesis reacts with [NiCl2 (PEt3 )2 ] by loss of a tBu group to give (η2 -3,4,5-tri-tert-butylcyclopentaphosphene)bis(triethylphosphane)nickel(0) (1). The previously unknown cyclopentaphosphene ring in 1 has an envelope conformation in solution and in the solid state, and the tBu groups adopt an all-trans configuration.
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