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Updated: Feb 11, 2026

Soft Lithographic Functionalization and Patterning Oxide-free Silicon and Germanium
Published on: December 16, 2011
A Route to a Germanium-Carbon Triple Bond: First Chemical Evidence for a Germyne
Christine Bibal1, Stéphane Mazières1, Heinz Gornitzka1
1Laboratoire Hétérochimie Fondamentale et Appliquée Université Paul Sabatier 118, route de Narbonne, 31062 Toulouse cedex 04 (France) Fax: (+33) 5-61-55-82-04.
Abstract:
Photolysis of a diazogermylene generates a germylene-carbene species, a resonance form of a germyne. Support for the intermediacy of the triply bonded form in the trapping reaction with an alcohol is provided by the fact that the diazo precursor does not behave as a germylene and that its photolysis product does not react with carbene traps such as 2,3-dimethylbutadiene. Hence, this is the first chemical evidence for a germyne. Ar=2,6-(iPr2 NCH2 )2 C6 H3 ; R=Me, tBu.
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