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Updated: Feb 11, 2026

Setup of Capillary Electrophoresis-Inductively Coupled Plasma Mass Spectrometry CE-ICP-MS for Quantification of Iron Redox Species FeII, FeIII
Published on: May 4, 2020
H2 O2 -Dependent Fe-Catalyzed Oxidations: Control of the Active Species
Yasmina Mekmouche1, Stéphane Ménage1, Carole Toia-Duboc1
1Laboratoire de Chimie et Biochimie des Centres Rédox Biologiques Université Joseph Fourier/DBMS/CEA, UMR CNRS 5047 17 rue des Martyrs, 38054 Grenoble Cédex 9 (France) Fax: (+33) 476889124.
Abstract:
Manipulation of the coordination sphere of an FeII ion can be used to tune the balance between different catalytic pathways for oxidation (OH. versus iron-based oxidant; see scheme). This reinvestigation of Fenton chemistry uses the iron complex shown as a mechanistic probe.
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