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Heterogeneous Dinuclear Rhodium(II) Hydroformylation Catalysts-Performance Evaluation and Silsesquioxane-Based
Mathias Nowotny1, Thomas Maschmeyer1, Brian F G Johnson2
1Laboratory for Applied Organic Chemistry and Catalysis Delft ChemTech, Delft University of Technology Julianalaan 136, 2628 BL Delft (The Netherlands) Fax: (+31) 15-2784289.
Abstract:
Supported, air stable, and reusable hydroformylation catalysts have been prepared by immobilizing dinuclear rhodium(II) complexes bearing ortho-metalated arylphosphane ligands on amorphous silica and mesoporous MCM-41 supports by phosphane tethers. The oligosilsesquioxane model complex of the catalytic site 1 has been prepared analogously and characterized by single-crystal X-ray diffraction analysis.
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