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Polymers02:34

Polymers

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The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
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When two atoms share electrons to complete their valence shells, they create a covalent bond. An atom's electronegativity—the force with which shared electrons are pulled towards an atom—determines how the electrons are shared. Molecules formed with covalent bonds can be either polar or nonpolar. Atoms with similar electronegativities form nonpolar covalent bonds; the electrons are shared equally. Atoms with different electronegativities share electrons unequally,...
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Covalently Linked Protein Regulators02:04

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Proteins can undergo many types of post-translational modifications, often in response to changes in their environment. These modifications play an important role in the function and stability of these proteins. Covalently linked molecules include functional groups, such as methyl, acetyl, and phosphate groups, and also small proteins, such as ubiquitin. There are around 200 different types of covalent regulators that have been identified.
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Network Covalent Solids02:18

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
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Covalent Bonding and Lewis Structures02:46

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Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
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Gold Nanoparticles with Covalently Attached Polymer Chains This work was supported by the Deutsche Forschungsgemeinschaft and by the Fonds der Chemischen Industrie. We are grateful to Prof. Dr. H. Weller, Institut für Physikalische Chemie der Universität Hamburg, for the transmission electron microscopy pictures and to Prof. Dr. M. Möller and Dipl.-Chem. Bernd Tartsch, Abteilung Organische Chemie III der Universität Ulm, for the scanning forcce microscopy investigations.

Angewandte Chemie (International ed. in English)·2002
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Related Experiment Video

Updated: Feb 11, 2026

Gold Nanoparticle Synthesis
13:42

Gold Nanoparticle Synthesis

Published on: July 10, 2021

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Gold Nanoparticles with Covalently Attached Polymer Chains.

Stefan Nuß1, Henrik Böttcher1, Hellmuth Wurm1

  • 1Institut für Makromolekulare Chemie Universität Hannover Am Kleinen Felde 30, 30167 Hannover (Germany) Fax: (+49) 511-762-4996.

Angewandte Chemie (International Ed. in English)
|May 2, 2018
PubMed
Summary
This summary is machine-generated.

Atom Transfer Radical Polymerization (ATRP) enables controlled graft-polymerization onto nanoparticles. This method allows precise adjustment of the polymer shell thickness while keeping the core nanoparticles intact.

Keywords:
colloidsgoldnanostructuresorganic-inorganic hybrid compositespolymers

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Area of Science:

  • Polymer Chemistry
  • Materials Science
  • Nanotechnology

Background:

  • Graft-polymerization onto nanoparticles is crucial for developing advanced materials.
  • Controlled radical polymerization techniques offer precise control over polymer architecture.

Purpose of the Study:

  • To investigate the suitability of Atom Transfer Radical Polymerization (ATRP) for nanoparticle graft-polymerization.
  • To demonstrate the ability to control polymer shell thickness on nanoparticles using ATRP.

Main Methods:

  • Utilizing the Atom Transfer Radical Polymerization (ATRP) mechanism for surface-initiated polymerization.
  • Grafting polymer chains onto pre-existing core nanoparticles without altering their structure.

Main Results:

  • ATRP is confirmed as an effective "living" polymerization method for nanoparticle modification.
  • The chain length of the grafted polymer, and thus shell thickness, can be precisely controlled by adjusting polymerization conditions.
  • Core nanoparticle integrity is maintained throughout the graft-polymerization process.

Conclusions:

  • Atom Transfer Radical Polymerization provides a versatile and controlled approach for creating polymer-grafted nanoparticles.
  • This technique allows for tunable polymer shell thickness, opening possibilities for tailored nanoparticle functionalities.