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Spatial Separation of Molecular Conformers and Clusters
Published on: January 9, 2014
[12.12]Paracyclophanedodecaynes C36 H8 and C36 Cl8 : The Smallest Paracyclophynes and Their Transformation into the
Yoshito Tobe1, Ryutaro Furukawa1, Motohiro Sonoda1
1Department of Chemistry, Faculty of Engineering Science Osaka University, and CREST, Japan Science and Technology Corporation (JST) Toyonaka, Osaka 560-8531 (Japan) Fax: (+81) 6-6850-6229.
Abstract:
The smallest [n.n]cyclophyne known, [12.12]paracyclophanedodecaynes C36 H8 and C36 Cl8 , were generated by [2+2] cycloreversion of its precursor under photolytic and mass spectrometric conditions. The stepwise loss of chlorine atoms from the anion of the octachloro derivative C36 Cl8- produced a carbon cluster anion C36- in the gas phase.
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