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Updated: Feb 11, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Solvothermal Synthesis of a 24-Nuclear, Cube-Shaped Squarato-oxovanadium(IV) Framework: [N(nBu)4 ]8 [V24 O24 (C4 O4
Johann Spandl1, Irene Brüdgam1, Hans Hartl1
1Freie Universität Berlin Institut für Chemie/Anorganische und Analytische Chemie Fabeckstrasse 34-36, 14195 Berlin (Germany) Fax: (+49) 30-83854003.
Abstract:
Polydentate bridging ligands can be used to link small polyoxo-alkoxo-metalate units to form supramolecular clusters. In the title compound, twelve μ4 -bridging squarato groups connect eight trinuclear methoxo-oxo-vanadate units to form a tetradodecanuclear cubic framework, in whose cavity six n-butyl groups of the tetra-n-butylammonium cations are anchored.
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