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Updated: Feb 11, 2026

Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles
Published on: October 27, 2018
Synthesis of the First 1,3,4-Triphosphole Complex
Rainer Streubel1, Udo Schiemann1, Peter G Jones1
1Institut für Anorganische und Analytische Chemie der Technischen Universität Braunschweig Postfach 3329, 38023 Braunschweig (Germany) Fax: (+49) 531-391-5387.
Abstract:
Surprisingly selective is the preparation of the novel 1,3,4-triphosphole complex 1 by insertion of a phosphaalkyne into a 1H-diphosphirene complex. NMR spectroscopic experiments and quantum-mechanical calculations indicate a small P-inversion barrier for the σ3 -phosphorus center in 1 as well as new possibilities of "π-tuning".
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