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[{(tBuC5 H4 )2 Nb(CO)}3 Co9 (CO)8 Te6 ⋅3 Cr(CO)5 ]: Unusual Stabilization of a Cubic Body-Centered Metal Telluride
Henri Brunner1, A Claudia Stückl1, Joachim Wachter1
1Institut für Anorganische Chemie der Universität Regensburg 93040 Regensburg (Germany) Fax: (+49) 941-943-4439.
Abstract:
The Te bridges of the [Co9 (CO)8 Te6 ] cube of 1 serve as anchors for three Cp$\rm{^{\prime }_{2}}$Nb(CO) (Cp'=tBuC5 H4 ) and three Cr(CO)5 fragments. This new principle allows the synthesis and structural comparison of clusters with 122-124 metal valence electrons.
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