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A Novel Hemiporphyrazine Comprising Three Isoindolediimine and Three Thiadiazole Units
Nagao Kobayashi1, Sayaka Inagaki1, Victor N Nemykin1
1Department of Chemistry Graduate School of Science, Tohoku University Sendai 980-8578 (Japan) Fax: (+81) 22-217-7719.
Abstract:
Incorporation of three metal ions (Ni or Cu) in the macrocyclic ring and the formation of hexamers following a 3+3 approach are novel features of the hemiporphyrazines (one example shown) formed by the condensation of 2,5-diamino-1,3,4-triazole with isoindolediimines. This is in contrast to the corresponding reactions with diaminotriazoles, which afford 2+2 products.
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