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[{Fe(C5 H4 )2 }3 {Ga(C5 H5 N)}2 ]: A Trinuclear Gallium-Bridged Ferrocenophane with a Carousel Structure
Peter Jutzi1, Norman Lenze1, Beate Neumann1
1Fakultät für Chemie der Universität Universitätsstrasse 25 33615 Bielefeld (Germany) Fax: (+49) 521-106-6026.
Abstract:
A molecular carousel, that is the appearance of the structure of the title compound [1⋅2 py], the first complex of a new structure type prepared by a highly selective condensation reaction from the equally new complex [Fe(C5 H4 GaMe2 )2 ]. The first gallium bridged [m.m]ferrocenophane [{Fe(C5 H4 )2 }2 {GaMe(C5 H5 N)} 2 ] is formed as an intermediate; this compound can also be prepared in a planned synthesis and can be converted into [1⋅2 py] by warming. The complex [1⋅2 py] as well as [1⋅2 Et2 O] and [1⋅2 DMSO], which were formed by donor exchange, offers various interesting properties, for example, [1⋅2 DMSO] can be reversibly oxidized to the mono-, di-, and trication.
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