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Updated: Feb 11, 2026

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Cyano-Bridged 4f-3d Coordination Polymers with a Unique Two-Dimensional Topological Architecture and Unusual Magnetic
Bao-Qing Ma1, Song Gao1, Gang Su2
1State Key Laboratory of Rare Earth Materials Chemistry and Applications PKU-HKU Joint Laboratory on Rare Earth Materials and Bioinorganic Chemistry Peking University, Beijing 100871 (P. R. China) Fax: (+86) 10-6275-1708.
Abstract:
Rings of 24 atoms form part of the two-dimensional structure of the novel compounds [NdM(bpym)(H2 O)4 (CN)6 ]⋅3 H2 O (M = Fe (1), Co (2); bpym = 2,2'-bipyrimidine). These compounds are the first two-dimensional cyano-bridged species containing lanthanide and transition metal centers. The structures and magnetic properties are investigated.
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