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Updated: Feb 11, 2026

Photoelectron Imaging of Anions Illustrated by 310 Nm Detachment of F−
Published on: July 27, 2018
Fullerene Anions: Unusual Charge Distribution in C706
Tamar Sternfeld1, Roy E Hoffman1, Ivan Aprahamian1
1Department of Organic Chemistry The Hebrew University of Jerusalem Jerusalem 91904 (Israel) Fax: (+972) 2-6527547.
Abstract:
The full NMR assignment by the INADEQUATE method clarifies the reduced aromaticity of the C706- ion (see picture; a-e indicate the five different carbon environments) relative to the neutral system, as well as the charge delocalization pattern. The reduction process was carried out with lithium in the presence of corannulene, which acts as an "electron shuttle".
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