Related Experiment Video
Updated: Feb 11, 2026

Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
A Two-Dimensional Polyrotaxane with Large Cavities and Channels: A Novel Approach to Metal-Organic Open-Frameworks by
Eunsung Lee1, Jaheon Kim1, Jungseok Heo1
1National Creative Research Initiative Center for Smart Supramolecules and Department of Chemistry Division of Molecular and Life Sciences Pohang University of Science and Technology San 31 Hyojadong, Pohang 790-784 (Republic of Korea) Fax: (+82) 54-279-8129.
Abstract:
A seven-membered molecular necklace composed of six copper ions and six pseudorotaxane units behaves as a secondary building block in the formation of a two-dimensional polyrotaxane network with large voids. This novel metal-organic framework allows size-selective anion exchange as well as the exchange of coordinated ligands. Thus a new synthetic strategy has been identified for modular porous solids which utilizes large, rigid, interlocked supermolecules as primary or secondary building blocks.
More Related Videos
Related Concept Videos
Oral Cavity
Teeth: The teeth are the hardest structures in our bodies. Humans have two sets of teeth throughout their lifetime: deciduous (baby) teeth and permanent teeth. Each tooth consists of several parts: the crown (visible part), the root (embedded in the jaw), enamel (hard outer...
Organic Compounds
Bonding in Metals
Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
Alkali Metals
Table 1: Properties of the alkali metals
Properties of Transition Metals

