Fuel-Driven Dissipative Self-Assembly of a Supra-Amphiphile in Batch Reactor

Dissipative self-assembly is an intriguing but challenging research topic in chemistry, materials science, physics, and biology because most functional self-assembly in nature, such as the organization and operation of cells, is actually an out-of-equilibrium system driven by energy dissipation. In this article, we successfully fabricated an I₂-responsive supra-amphiphile by a PEGylated poly(amino acid) and realize its dissipative self-assembly in batch reactor by coupling it with the redox reaction between NaIO₃ and thiourea, in which I₂ is an intermediate product. The formation and dissipative self-assembly of the supra-amphiphile can be repeatedly initiated by adding the mixture of NaIO₃ and thiourea, which herein acts as "chemical fuel", while the lifetime of the transient nanostructures formed by the dissipative self-assembly is easily tuned by altering thiourea concentration in the "chemical fuel". Furthermore, as an application demo, the dissipative self-assembly of the supra-amphiphile is examined to control dispersion of multiwalled carbon nanotubes in water, exhibiting a good performance of organic pollutant removal.