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Stepwise radical cation Diels-Alder reaction via multiple pathways.

Ryo Shimizu1, Yohei Okada2, Kazuhiro Chiba1

  • 1Department of Applied Biological Science, Tokyo University of Agriculture and Technology, 3-5-8 Saiwai-cho, Fuchu, Tokyo 183-8509, Japan.

Beilstein Journal of Organic Chemistry
|May 3, 2018
PubMed
Summary

This study reveals a novel electrocatalytic method for radical cation Diels-Alder reactions using aryl vinyl ethers. The reaction proceeds via a rare stepwise mechanism involving single-electron transfer (SET).

Keywords:
Diels–Alder reactionradical cationrearrangementsingle electron transferstepwise

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