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Updated: Feb 11, 2026

Development of Heterogeneous Enantioselective Catalysts using Chiral Metal-Organic Frameworks MOFs
Published on: January 17, 2020
A highly stable and hierarchical tetrathiafulvalene-based metal-organic framework with improved performance as a
Manuel Souto1, Andrea Santiago-Portillo2, Miguel Palomino3
1Instituto de Ciencia Molecular (ICMol) , Universitat de València , c/Catedrático José Beltrán, 2 , 46980 Paterna , Spain .
Abstract:
Herein we report the synthesis of a tetrathiafulvalene (TTF)-based MOF, namely MUV-2, which shows a non-interpenetrated hierarchical crystal structure with mesoporous one-dimensional channels of ca. 3 nm and orthogonal microporous channels of ca. 1 nm. This highly stable MOF (aqueous solution with pH values ranging from 2 to 11 and different organic solvents), which possesses the well-known [Fe3(μ3-O)(COO)6] secondary building unit, has proven to be an efficient catalyst for the aerobic oxidation of dibenzothiophenes.
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