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A Dimeric η1 ,η5 -Germole Dianion Bridged Titanium(III) Complex with a Multicenter Ti-Ge-Ge-Ti Bond
Zhaowen Dong1, Oliver Janka1,2, Jutta Kösters2
1Institut für Chemie, Carl von Ossietzky Universität Oldenburg, Carl von Ossietzky-Str. 9-11, 26129, Oldenburg, Germany.
Abstract:
Dimeric germole dianion bridged TiIII and ZrIV complexes have been synthesized. In these complexes, the germole dianion adopts a formal η1 ,η5 coordination to the two metal centers. The bonding situation in these bridged dimers is dominated by a covalent Ge-Ge interaction that results, for example, in a strong antiferromagnetic coupling of the d1 Ti centers.
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