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Updated: Feb 10, 2026

Laboratory-determined Phosphorus Flux from Lake Sediments as a Measure of Internal Phosphorus Loading
Published on: March 6, 2014
Sustainable Phosphorus Chemistry: A Silylphosphide Synthon for the Generation of Value-Added Phosphorus Chemicals
1Van 't Hoff Institute for Molecular Sciences, Research Priority Area Sustainable Chemistry, University of Amsterdam, Science Park 904, PO Box 94157, 1090 GD, Amsterdam, The Netherlands.
Abstract:
Avoiding white phosphorus: Cummins and Geeson have recently described the conversion of phosphoric acid into the novel bis(trichlorosilyl)phosphide anion, which serves as a key intermediate in the synthesis of organophosphines, hexafluorophosphate, and phosphine gas in a reaction sequence that does not rely on white phosphorus.
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