Discriminating between Different Heavy Metal Ions with Fullerene-Derived Nanoparticles

A novel type of graphene-like nanoparticle, synthesized by oxidation and unfolding of C₆₀ buckminsterfullerene fullerene, showed multiple and reproducible sensitivity to Cu²⁺, Pb²⁺, Cd²⁺, and As(III) through different degrees of fluorescence quenching or, in the case of Cd²⁺, through a remarkable fluorescence enhancement. Most importantly, only for Cu²⁺ and Pb²⁺, the fluorescence intensity variations came with distinct modifications of the optical absorption spectrum. Time-resolved fluorescence study confirmed that the common origin of these diverse behaviors lies in complexation of the metal ions by fullerene-derived carbon layers, even though further studies are required for a complete explanation of the involved processes. Nonetheless, the different response of fluorescence and optical absorbance towards distinct cationic species makes it possible to discriminate between the presence of Cu²⁺, Pb²⁺, Cd²⁺, and As(III), through two simple optical measurements. To this end, the use of a three-dimensional calibration plot is discussed. This property makes fullerene-derived nanoparticles a promising material in view of the implementation of a selective, colorimetric/fluorescent detection system.