Metal Actuated Ring Translocation Switches in Water
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Updated: Feb 10, 2026

Real-Time DC-dynamic Biasing Method for Switching Time Improvement in Severely Underdamped Fringing-field Electrostatic MEMS Actuators
Published on: August 15, 2014
Hang Yin1, Roselyne Rosas2, Didier Gigmes3
1State Key Laboratory of Quality Research in Chinese Medicine, and Institute of Chinese Medical Sciences , University of Macau, Avenida da Universidade , Taipa , Macau SAR , China.
Abstract:
Among a series of metal ions in water, silver is the only one to remotely and reversibly switch cucurbit[7]uril (CB[7]) movements (translocation or uptake) on a rigid and linear three-station viologen-phenylene-imidazole ( V-P-I) derivative, avoiding undesired pH actuation. 1H NMR, UV-vis spectroscopy, mass spectrometry, ITC, and modeling were combined to show that ring translocation or uptake along a molecular thread is possible in water by Ag+ as a metal stimulus.
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