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Updated: Feb 10, 2026

Automated 90Sr Separation and Preconcentration in a Lab-on-Valve System at Ppq Level
Published on: June 6, 2018
Separation and preconcentration of actinides from concentrated nitric acid by extraction chromatography in
Marion Losno1, Julien Pellé1, Mylène Marie1
1Den - Service d'Etudes Analytiques et de Réactivité des Surfaces (SEARS), CEA, Université Paris-Saclay, F-91191 Gif sur Yvette, France.
Abstract:
An original method of monolith impregnation in microsystem for the analysis of radionuclides in nitric acid is reported. Three microcolumns made of monolith poly(AMA-co-EDMA) were impregnated in COC microsystems. The robustness of the microsystems in nitric acid media until 8 M was demonstrated. High exchange capacity and affinity for tetravalent and hexavalent actinides in concentrated nitric media were obtained. The retention characteristics of the microcolumns impregnated by TBP, TBP-CMPO and DAAP were compared with those of the equivalent commercial particulate resins TBP™, TRU™ and UTEVA™ respectively. The separation of U, Th and Eu was validated in a classical microsystem and a procedure is proposed in a centrifugal microsystem.
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