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Isomerism in double-pillared-layer coordination polymers - structures and photoreactivity.

In-Hyeok Park1, Huiyeong Ju2, Kihwan Kim2

  • 1Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore.

Iucrj
|May 17, 2018
PubMed
Summary

Two isomeric coordination polymers with zinc(II) exhibit distinct pore structures and photoreactivity due to varied carboxylate bonding. This highlights how subtle structural changes impact material properties and reactivity.

Keywords:
MOFscoordination polymerscrystal engineeringcrystallization and crystal growthcyclo­addition reactionsmetal–organic frameworkssingle-crystal-to-single-crystal transformationssolid-state transformationsstructural isomerismsupra­molecular isomerism

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