A Full-Visible-Spectrum Invisibility Cloak for Mesoscopic Metal Wires

Structured metals can sustain a very large scattering cross-section that is induced by localized surface plasmons, which often has an adverse effect on their use as transparent electrodes in displays, touch screens, and smart windows due to an issue of low clarity. Here, we report a broadband optical cloaking strategy for the network of mesoscopic metal wires with submicrometer to micrometer diameters, which is exploited for manufacturing and application of high-clarity metal-wires-based transparent electrodes. We prepare electrospun Ag wires with 300-1800 nm in diameter and perform a facile surface oxidation process to form Ag/Ag₂O core/shell heterogeneous structures. The absorptive Ag₂O shell, together with the coating of a dielectric cover, leads to the cancellation of electric multipole moments in Ag wires, thereby drastically suppressing plasmon-mediated scattering over the full visible spectrum and rendering Ag wires to be invisible. Simultaneously with the effect of invisibility, the transmittance of Ag/Ag₂O wires is significantly improved compared to bare Ag wires, despite the formation of an absorptive Ag₂O shell. As an application example, we demonstrate that these invisible Ag wires serve as a high-clarity, high-transmittance, and high-speed defroster for automotive windshields.