Transverse vibration driven large uniaxial negative and zero thermal expansion in boron bridged REPt₃B framework...

In this work anomalous uniaxial thermal expansion behaviour at low temperatures along the c-direction of the tetragonal phase of different members of the antiperovskite REPt3B (RE = Sm, Gd-Tm) compounds is reported. Negative or zero thermal expansion (NTE/ZTE) behaviour in these compounds arises due to the transverse vibration of boron atoms in the linear Pt-B-Pt linkage. The coefficient of thermal expansion along the c-axis tends to become more negative in annealed compounds in comparison to those estimated for as-cast samples. While the as-cast TmPt3B and HoPt3B exhibit essentially ZTE behaviour, the NTE coefficient of annealed GdPt3B (∼-28 ppm K-1) is found to be even larger than that of the well known framework material ZrW2O8 (∼-9 ppm K-1) reported in the literature.