Doping ZnO Electron Transport Layers with MoS₂ Nanosheets Enhances the Efficiency of Polymer Solar Cells

In this study, we incorporated molybdenum disulfide (MoS₂) nanosheets into sol-gel processing of zinc oxide (ZnO) to form ZnO:MoS₂ composites for use as electron transport layers (ETLs) in inverted polymer solar cells featuring a binary bulk heterojunction active layer. We could effectively tune the energy band of the ZnO:MoS₂ composite film from 4.45 to 4.22 eV by varying the content of MoS₂ up to 0.5 wt %, such that the composite was suitable for use in bulk heterojunction photovoltaic devices based on poly[bis(5-(2-ethylhexyl)thien-2-yl)benzodithiophene- alt-(4-(2-ethylhexyl)-3-fluorothienothiophene)-2-carboxylate-2,6-diyl] (PTB7-TH)/phenyl-C₇₁-butryric acid methyl ester (PC₇₁BM). In particular, the power conversion efficiency (PCE) of the PTB7-TH/PC₇₁BM (1:1.5, w/w) device incorporating the ZnO:MoS₂ (0.5 wt %) composite layer as the ETL was 10.1%, up from 8.8% for the corresponding device featuring ZnO alone as the ETL, a relative increase of 15%. Incorporating a small amount of MoS₂ nanosheets into the ETL altered the morphology of the ETL and resulted in enhanced current densities, fill factors, and PCEs for the devices. We used ultraviolet photoelectron spectroscopy, synchrotron grazing incidence wide-/small-angle X-ray scattering, atomic force microscopy, and transmission electron microscopy to characterize the energy band structures, internal structures, surface roughness, and morphologies, respectively, of the ZnO:MoS₂ composite films.