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Updated: Feb 10, 2026

Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
Published on: October 10, 2016
Cyclic Anion-Responsive π-Electronic Molecules That Overcome Energy Losses Induced by Conformation Changes
Shunsuke Kaname1, Yohei Haketa1, Nobuhiro Yasuda2
1Department of Applied Chemistry, College of Life Sciences , Ritsumeikan University , Kusatsu 525-8577 , Japan.
Abstract:
Preorganized structures suitable for anion binding were prepared by introducing dipyrrolyldiketone BF2 complexes as acyclic anion-responsive π-electronic molecules into macrocycles. Pyrrole-inverted conformations, which typically present low stability in the case of acyclic derivatives, were obtained by covalent linkages through ring-closing olefin metathesis, exhibiting extremely high affinity for different anions.
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