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Updated: Feb 10, 2026

Visible-light Induced Reduction of Graphene Oxide Using Plasmonic Nanoparticle
Published on: September 22, 2015
Metal oxide nanoparticle-modified graphene oxide for removal of elemental mercury
Yuxi Liu1,2, Gang Chen1, Chong Tian3
1Wuhan Second Ship Design and Research Institute , Wuhan , P.R. People's Republic of China.
Abstract:
Mercury is an extremely toxic element that is primarily released by anthropogenic activities and natural sources. Controlling Hg emissions, especially from coal combustion flue gas, is of practical importance in protecting the environment and preventing human health risks. In the present work, three metal oxides (MnO2, CuO, and ZnO) were loaded on graphene oxide (GO) sorbents (designated as MnO2-GO, CuO-GO, and ZnO-GO). All three adsorbents were successfully synthesized and were well characterized using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). The results indicated that the metal oxide nanoparticles (NPs) successfully decorated the GO. The elemental Hg adsorption capabilities of the three sorbents were subsequently evaluated using an in-house built setup for cold vapour atomic fluorescence spectrophotometry (CVAFS) with argon as the carrier gas for mercury detection. The testing temperature ranged from 50°C to 200°C at intervals of 50°C. MnO2-GO showed an excel lent Hg0 adsorption capacity via chemisorption from 50 to 150°C and a mercury removal efficiency as high as 85% at 200°C, indicating that the MnO2-NP-modified GO is applicable for enhancing gas-phase elemental mercury removal. However, neither CuO-GO nor ZnO-GO performed well. This work provides useful insights into the development of novel sorbent materials for the elemental mercury removal from flue gases.
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