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Defect state-induced efficient hot electron transfer in Au nanoparticles/reduced TiO2 mesocrystal photocatalysts
Jiawei Xue1, Ossama Elbanna, Sooyeon Kim
1The Institute of Scientific and Industrial Research (SANKEN), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka 567-0047, Japan. majima@sanken.osaka-u.ac.jp.
Abstract:
We investigated Au/TiO2 mesocrystals as plasmonic photocatalyst prototypes using single-particle photoluminescence (PL) spectroscopy combined with finite-difference time-domain (FDTD) simulations, and found that introduction of defect states builds up a channel for hot electrons with energies lower than the Schottky barrier height to transfer to the semiconductor.
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