Highly Efficient Visible-Light-Driven Photocatalytic Hydrogen Production on CdS/Cu₇S₄/g-C₃N₄ Ternary Heterostructures

Hydrogen production through photocatalytic water splitting has attracted much attention because of its potential to solve the issues of environmental pollution and energy shortage. In this work, CdS/Cu₇S₄/g-C₃N₄ ternary heterostructures are fabricated by ion exchange between CdS and Cu⁺ and subsequent ultrasonication-assisted self-assembly of CdS/Cu₇S₄ and g-C₃N₄, which provide excellent visible-light photocatalytic activity for hydrogen evolution without any noble metal cocatalyst. With the presence of p-n junction, tuned band gap alignments, and higher charge carrier density in the CdS/Cu₇S₄/g-C₃N₄ ternary heterostructures that can effectively promote the spatial separation and prolong the lifetime of photogenerated electrons, a high hydrogen evolution rate of 3570 μmol g^-1 h^-1, an apparent quantum yield of 4.4% at 420 nm, and remarkable recycling stability are achieved. We believe that the as-synthesized CdS/Cu₇S₄/g-C₃N₄ ternary heterostructures can be promising noble metal-free catalysts for enhanced hydrogen production from photocatalytic water splitting.