Synthesis of Rh(iii) thiophosphinito pincer hydrido complexes by base-free C-H bond activation at room temperature
G Vlahopoulou1, S Möller, J Haak
1Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany. detlef.heller@catalysis.de torsten.beweries@catalysis.de.
Abstract:
Rhodium(iii) thiophosphinito pincer hydrido complexes were synthesised by C-H activation under exceptionally mild conditions at room temperature without additional base or irradiation and fully characterised by multinuclear NMR spectroscopy and X-ray crystallography. C-H activation under these mild conditions contrasts with the reactivity of related systems with POCOP ligands.
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