Enhanced fluoride removal behaviour and mechanism by dicalcium phosphate from aqueous solution

Dicalcium phosphate was prepared by ethylenediaminetetraacetic acid as a calcium chelating agent, and further explored to remove the fluoride ions from aqueous solution. The as-prepared samples main existed in the monetite phase from the result of XRD. The dried sample consisted of small nanoparticles and displayed irregular particles with a size of ca. 3 μm due to the agglomeration. The fluoride removal ability was evaluated by batch adsorption experiments. The as-prepared adsorbent exhibited the enhanced fluoride removal behaviour with the maximum adsorption capacity of 66.72 mg/g from the Langmuir isotherm model, which was higher than that of other previously reported calcium phosphate. The adsorbent could be utilized in the wide pH range of 3-10. The adsorption kinetics could be better described by the pseudo-second-order model than first-second-order model. The co-existing anions had a negligible influence on the fluoride adsorption. The investigation of adsorption mechanism suggested that the chemical reaction and/or dissolution - precipitation mechanism should be dominant in the fluoride adsorption process, accompanying with electronic interaction and ions exchange, which enhanced the fluoride removal performance.