High arsenic groundwater in the Guide basin, northwestern China: Distribution and genesis mechanisms

High arsenic (As) groundwater has been found in Pliocene confined aquifers at depths from 100 to 300 m of the Guide basin, but little is known on the main hydrogeochemical processes leading to its elevated concentrations. Ninety-seven water samples and fifty-three sediment samples were collected for chemical and/or isotopic analysis. Concentrations of As in groundwater of confined aquifer range from 9.9 to 377 μg/L (average 109 μg/L), which generally show a sharply increasing trend along with NH₄⁺, HCO₃^-, CO₃^2- and TOC along the inferred flow path, while NO₃^-, SO₄^2-/Cl^- and redox potential (Eh) have decreasing trends. Results of sequential extraction show that As bound to amorphous and crystalline Fe oxide minerals are the main As forms, accounting for around 50% of total As in sediments. Reductive dissolution of As-bearing Fe(III) oxide minerals under reducing conditions in confined aquifers lead to the mobilization of As in groundwater. In addition, alkaline environment and high concentrations of HCO₃^- and CO₃^2- may make contributions to As enrichment in groundwater. High As groundwater in confined aquifer continuously flows out on the ground surface through tens of artesian wells, which may potentially contaminate low As groundwater in unconfined aquifer. Thus, further investigation is needed to evaluate long-term variations of water chemistry of low As groundwater and assess vulnerability of unconfined aquifer to As contamination.