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Published on: May 11, 2019
Tensile-Strain-Dependent Spin States in Epitaxial LaCoO_{3} Thin Films
Y Yokoyama1,2, Y Yamasaki3,4,5, M Taguchi6
1Institute for Solid State Physics, University of Tokyo, Chiba 277-8581, Japan.
Abstract:
The spin states of Co^{3+} ions in perovskite-type LaCoO_{3}, governed by the complex interplay between the electron-lattice interactions and the strong electron correlations, still remain controversial due to the lack of experimental techniques which can directly detect them. In this Letter, we revealed the tensile-strain dependence of spin states, i.e., the ratio of the high- and low-spin states, in epitaxial thin films and a bulk crystal of LaCoO_{3} via resonant inelastic soft x-ray scattering. A tensile strain as small as 1.0% was found to realize different spin states from that in the bulk.
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